The reaction of the cluster anion [Os4(µ-Cl)(CO)13]–1 with [Au(PPh3)]– affords the cluster [Os3{µ-AuOs(CO)4(PPh3)}(µ-Cl)(CO)10]2 which represents the first example in which an Os(CO)4 fragment has been inserted in to a gold–phosphine bond; the structure of 2 has been established by a single-crystal X-ray analysis.
C. Cathey, J. Lewis, P. R. Raithby and M. C. R. de Arellano, J. Chem. Soc., Dalton Trans., 1994, 3331 DOI: 10.1039/DT9940003331
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