Issue 5, 1995
From the journal:

Journal of the Chemical Society, Dalton Transactions

Dalton communications. Effect of amine substituents and neutral leaving groups on the activation volume for aquation of octahedral pentaamine complexes of CrIII and RhIII

Gabriel González,   Manuel Martinez  and  Elisa Rodríguez  

Abstract

The activation volumes were obtained for the aquation reactions of [M(RNH2)5L]3+(M = Cr, R = Me, L = Me2SO, HCONMe2 or MeCONMe2; M = Rh, R = H or Me, L = Me2SO or HCONMe2); they are in accord with the existence of a dissociative shift in the substitution mechanism, not only with the size of the substituent R, but also with the size of the leaving ligands L.

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Article information

DOI
https://doi.org/10.1039/DT9950000891
Article type
Paper

J. Chem. Soc., Dalton Trans., 1995, 891-892

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Dalton communications. Effect of amine substituents and neutral leaving groups on the activation volume for aquation of octahedral pentaamine complexes of CrIII and RhIII

G. González, M. Martinez and E. Rodríguez, J. Chem. Soc., Dalton Trans., 1995, 891 DOI: 10.1039/DT9950000891

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