Issue 4, 1996
From the journal:

Journal of the Chemical Society, Dalton Transactions

Cationic, four-co-ordinate, bis(organotransition metal)bismuth(III) complexes

Claire J. Carmalt,   Louis J. Farrugia  and  Nicholas C. Norman  

Abstract

The ionic complex [Bi{OP(NMe2)3}2{Fe(CO)2(η-C5H5)}2][PF6] has been prepared and its crystal structure determined and compared with that of the valence isoelectronic anion [BiCl2{Fe(CO)2(η-C5H5)}2]–. Both structures have a four-co-ordinate bismuth centre with a geometry best described as equatorially vacant, trigonal bipyramidal in which the Fe(CO)2(η-C5H5) fragments are in the equatorial positions. The structure of [BiCl{Mo(CO)3(η-C5H4Me)}2] has also been determined and is compared with that of [BiCl{Mo(CO)3(η-C5H5)}2].

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Article information

DOI
https://doi.org/10.1039/DT9960000455
Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 455-459

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Cationic, four-co-ordinate, bis(organotransition metal)bismuth(III) complexes

C. J. Carmalt, L. J. Farrugia and N. C. Norman, J. Chem. Soc., Dalton Trans., 1996, 455 DOI: 10.1039/DT9960000455

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