Issue 8, 1996

Structure and reactivity of [{Te(NMe2)2}]; application to the preparation of metalloorganic tellurium(II) compounds

Abstract

Condensation of the highly reactive complex [{Te(NMe2)2}]1, prepared by the reaction of TeCl4 and Li[NMe2](1 : 4 equivalents), with various organic acids has been used as a route to tellurium(II) metalloorganic complexes. The crystal structures of 1 and of Te(SCPh3)22, formed by the reaction of 1 with Ph3CSH(1 : 2 equivalents), have been determined.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 1727-1730

Structure and reactivity of [{Te(NMe2)2}]; application to the preparation of metalloorganic tellurium(II) compounds

R. E. Allan, H. Gornitzka, J. Kärcher, M. A. Paver, M. Rennie, C. A. Russell, P. R. Raithby, D. Stalke, A. Steiner and D. S. Wright, J. Chem. Soc., Dalton Trans., 1996, 1727 DOI: 10.1039/DT9960001727

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