Homochiral hydroxyphosphoryl compounds, L, such as the novel camphor-based (1R)-endo,endo-3S-(diphenylphosphoryl)-2R-hydroxybornane, have been found to be prevented from behaving as bidentate ligands in the epoxidation catalysts [MoO(O2)2L(H2O)] by unexpectedly strong multiple-bond delocalisation producing near linear Mo–O–P angles.
R. J. Cross, L. J. Farrugia, P. D. Newman, R. D. Peacock and D. Stirling, J. Chem. Soc., Dalton Trans., 1996, 4149 DOI: 10.1039/DT9960004149
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