Issue 0, 1975
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Formation and dissociation of C2 from high temperature pyrolysis of acetylene

W. H. Beck  and  J. C. Mackie  

Abstract

Kinetics of formation and decay of C2 produced by passing shock waves through dilute C2H2+ Ar mixtures were studied at temperatures in the range 4860–6920 K. The kinetics of formation of C2 were in essential agreement with a postulated simple two-step dissociation of C2H2 by Ar. The rate constant for the dissociation of C2 by Ar was found to be kC2,Ar= 10–(9.21 ± 0.27) exp(–581 ± 59 kJ mol–1/RT) cm3 molecule–1 s–1.

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Article information

DOI
https://doi.org/10.1039/F19757101363
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1975,71, 1363-1371

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Formation and dissociation of C2 from high temperature pyrolysis of acetylene

W. H. Beck and J. C. Mackie, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 1363 DOI: 10.1039/F19757101363

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