Issue 0, 1976
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Self-heating in the decomposition of 3-methyl-3-chlorodiazirine: determination of reaction exothermicity and correction of arrhenius parameters

(Mrs)Wendy H. Archer  and  Brian J. Tyler  

Abstract

The gas-phase decomposition of 3-methyl-3-chlorodiazirine(I) has been re-investigated using direct measurement of the reactant gas temperature to demonstrate the occurrence of self-heating during reaction. In addition, the thermal conductivity of (I) has been measured at 298 and 348 K. From these data ΔH°f(I) is determined as 55.6 ± 9.5 kcal mol–1 and a significant error in the earlier measurement of the Arrhenius parameters for the low pressure decomposition reaction is corrected.

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Article information

DOI
https://doi.org/10.1039/F19767201448
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1976,72, 1448-1455

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Self-heating in the decomposition of 3-methyl-3-chlorodiazirine: determination of reaction exothermicity and correction of arrhenius parameters

W. H. Archer and B. J. Tyler, J. Chem. Soc., Faraday Trans. 1, 1976, 72, 1448 DOI: 10.1039/F19767201448

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