Issue 0, 1979
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Spectroscopic study on the surface structure and environment of fixed Mo catalysts prepared by use of Mo(π-C3H5)4

Yasuhiro Iwasawa  and  Sadao Ogasawara  

Abstract

The surface structure, the environment and the distribution of the active sites of fixed Mo catalysts were spectroscopically investigated and compared with those of conventional catalysts made by an impregnation method. The fixed catalysts were found to have the tetrahedral dioxostructure of six-valent molybdenum with coordination unsaturation, uniformly and atomically populated at silica or alumina surface, in a different environment from that of the impregnation catalysts. Such properties of molybdenum are thought to be essential factors for catalytic action in the abstraction of a hydrogen atom(hydride) from the C—H bond of a reactant. There are three different types of molybdenum species in the impregnation silica catalysts.

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Article information

DOI
https://doi.org/10.1039/F19797501465
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1979,75, 1465-1476

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Spectroscopic study on the surface structure and environment of fixed Mo catalysts prepared by use of Mo(π-C3H5)4

Y. Iwasawa and S. Ogasawara, J. Chem. Soc., Faraday Trans. 1, 1979, 75, 1465 DOI: 10.1039/F19797501465

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