Issue 7, 1982
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Radiolysis of tetrachloromethane

Martyn C. R. Symons,   Emanuele Albano,   Trevor F. Slater  and  Aldo Tomasi  

Abstract

Electron spin resonance studies of tetrachloromethane after exposure to 60Co γ-rays at 77 K reveal the formation of ·CCl3 and CCl˙+4 radicals. On warming in the presence of spin-traps, or on irradiating fluid solutions, nitroxide radical adducts have been detected that are characteristic of ·CCl3 and chlorine atom adducts. In the light of this evidence and that of other investigators a mechanism for the radiolysis of tetrachloromethane is postulated.

In the presence of oxygen, ·CCl3 radicals are converted into Cl3COO· radicals. The use of spin-traps to detect these radicals is described and evaluated.

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Article information

DOI
https://doi.org/10.1039/F19827802205
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1982,78, 2205-2214

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Radiolysis of tetrachloromethane

M. C. R. Symons, E. Albano, T. F. Slater and A. Tomasi, J. Chem. Soc., Faraday Trans. 1, 1982, 78, 2205 DOI: 10.1039/F19827802205

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