Issue 2, 1987
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Kinetics of reaction with hydroxide ions and solubilities of iron(II) complex cations in aqueous urea solutions. Derivation of transfer chemical potentials for initial and transition states

Michael J. Blandamer,   John Burgess,   Andrew W. Hakin,   Pilar Guardado,   Sumchairuk Nuttall  and  Stojan Radulovic  

Abstract

The solubilities in water at 298.15 K of perchlorates formed by three iron(II) complex cations containing di-imine ligands increase when urea is added. The complex salts are [Fe(phen)3](ClO4)2, [Fe(gmi)3](ClO4)2 and [Fe(bsb)3](ClO4)2. The solubility data are combined with solubility data for other salts in aqueous urea solutions, and analysed to obtain transfer chemical potentials for single ions using the tetraphenylarsonium tetraphenylboronate (TATB) extrathermodynamic assumption. The transfer parameters for the first two iron(II) complex cations listed above and for hydroxide ions are combined with kinetic data to yield the effects of added urea on transfer parameters for initial and transition states. The modest change in rate constants for reaction between hydroxide ions and iron(II)–phen complex in aqueous solution masks quite striking changes in reference chemical potentials of initial and transition states when urea is added.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/F19878300559
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1987,83, 559-569

Permissions

Request permissions

Kinetics of reaction with hydroxide ions and solubilities of iron(II) complex cations in aqueous urea solutions. Derivation of transfer chemical potentials for initial and transition states

M. J. Blandamer, J. Burgess, A. W. Hakin, P. Guardado, S. Nuttall and S. Radulovic, J. Chem. Soc., Faraday Trans. 1, 1987, 83, 559 DOI: 10.1039/F19878300559

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements