Issue 0, 1973
From the journal:

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

Dihedral angle of biphenyl in solution and the molecular force field

Valerie J. Eaton  and  Derek Steele  

Abstract

The dihedral angle between the rings of biphenyl is determined to be 32 ± 2° in the molten and solution states. Observed vibrational frequency shifts on going from the planar configuration held in the crystal to the non-planar solution state are compared with computed frequency shifts. To improve the accuracy in the computed frequencies the force constants were refined. The values of the force constants associated with the inter-ring bond are discussed.

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Article information

DOI
https://doi.org/10.1039/F29736901601
Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1973,69, 1601-1608

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Dihedral angle of biphenyl in solution and the molecular force field

V. J. Eaton and D. Steele, J. Chem. Soc., Faraday Trans. 2, 1973, 69, 1601 DOI: 10.1039/F29736901601

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