Issue 2, 1977
From the journal:

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

Experimental (ESCA) and theoretical (SCF–MO) determination of the oxidation state of sulphur in bis(2-carboxyphenyl) sulphur dihydroxide dilactone

Giannoula Theodorakopoulos,   Imre G. Csizmadia,   Michael A. Robb,   árpád Kucsman  and  István Kapovits  

Abstract

Inner shell ionization potentials have been evaluated for some diphenyl substituted (“model” unsubstituted) sulphides, sulphoxides, sulphones and sulphuranes by means of X-ray photoelectron spectroscopy (non-empirical m.o. calculation).

A good linear correlation is obtained between formal S oxidation state and S 2p ionization potentials for both the experimental and theoretical results, leading to an assignment of an S oxidation state of 4 in bis-(2-carboxyphenyl) sulphur dihydroxide dilactone.

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Article information

DOI
https://doi.org/10.1039/F29777300293
Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1977,73, 293-297

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Experimental (ESCA) and theoretical (SCF–MO) determination of the oxidation state of sulphur in bis(2-carboxyphenyl) sulphur dihydroxide dilactone

G. Theodorakopoulos, I. G. Csizmadia, M. A. Robb, Á. Kucsman and I. Kapovits, J. Chem. Soc., Faraday Trans. 2, 1977, 73, 293 DOI: 10.1039/F29777300293

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