The He(I) photoelectron spectrum of the ClO(X2Πi) radical has been recorded and interpreted with the aid of ab initioΔSCF calculations. Of the expected eleven ionic states, five have been positively identified. The remaining six ionic states have been shown to occur within a 1.5 eV energy range and contribute to a broad band centred at 14.68 eV.
D. K. Bulgin, J. M. Dyke, N. Jonathan and A. Morris, J. Chem. Soc., Faraday Trans. 2, 1979, 75, 456 DOI: 10.1039/F29797500456
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