Issue 6, 1983

Absorption spectra of substituted biphenyl and related cations in solid argon and a comparison with photoelectron spectra

Abstract

One-photon and two-photon matrix photoionization experiments have been performed with substituted biphenyls, fluorene and 9,10-dihydrophenanthrene. Absorption spectra in the red region correlate with photoelectron spectra for a π3π6 transition and indicate a relaxation of the dihedral angle upon ionization. Sharp ultraviolet absorption spectra are assigned to ππ* transitions for the matrix-isolated cations.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1983,79, 885-895

Absorption spectra of substituted biphenyl and related cations in solid argon and a comparison with photoelectron spectra

L. Andrews, R. T. Arlinghaus and C. K. Payne, J. Chem. Soc., Faraday Trans. 2, 1983, 79, 885 DOI: 10.1039/F29837900885

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