Issue 9, 1983

Absorption spectrum of the carbon tetrachloride molecular cation in noble-gas matrices

Abstract

Carbon tetrachloride diluted in argon, krypton or xenon and subjected to vacuum-ultraviolet radiation during and after condensation gave strong photosensitive absorptions at 425, 430 and 455 nm, respectively, which are assigned to CCl4+. This study suggests that absorptions in this region following radiolysis of CCl4 in hydrocarbon glasses are probably due to CCl4+ as well and that structural relaxation follows ionization of CCl4 in the solid phase.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1983,79, 1417-1424

Absorption spectrum of the carbon tetrachloride molecular cation in noble-gas matrices

L. Andrews, B. J. Kelsall, J. H. Miller and B. W. Keelan, J. Chem. Soc., Faraday Trans. 2, 1983, 79, 1417 DOI: 10.1039/F29837901417

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