Volume 12, 1977
From the journal:

Faraday Symposia of the Chemical Society

Phase formation in the underpotential deposition of metals

Alan Bewick,   Jovan Jovićević  and  Brian Thomas  

Abstract

The structures of the two-dimensional layers formed in the underpotential deposition of lead onto carefully prepared single crystals of copper are shown to depend upon the substrate orientation for (111), (100) and (110) surfaces. Nucleative growth processes are observed for first order and for higher order phase transitions. Comparison is made with the behaviour observed on silver substrates and the differences are ascribed to the change in atomic radius and in eletronegativity. Formation of the underpotential layer is shown to be a necessary precursor to overpotential deposition, the mechanism of which is markedly dependent on substrate orientation.

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Article information

DOI
https://doi.org/10.1039/FS9771200024
Article type
Paper

Faraday Symp. Chem. Soc., 1977,12, 24-35

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Phase formation in the underpotential deposition of metals

A. Bewick, J. Jovićević and B. Thomas, Faraday Symp. Chem. Soc., 1977, 12, 24 DOI: 10.1039/FS9771200024

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