Issue 0, 1969

Calorimetrically determined log K, ΔH°, and ΔS° values for the interaction of sulphate ion with H+, Na+, and K+ in the presence of tetra-n-alkylammonium ions

Abstract

Log K, ΔH°, and ΔS° values for the interaction in aqueous solution at 25° of SO42– with H+, Na+, and K+, and of ClO4 with R4N+(R = Me, Et, and Prn), have been determined using a calorimetric titration procedure. The results indicate that the tetra-n-alkylammonium ions do not associate appreciably with SO42–.

Article information

Article type
Paper

J. Chem. Soc. A, 1969, 45-47

Calorimetrically determined log K, ΔH°, and ΔS° values for the interaction of sulphate ion with H+, Na+, and K+ in the presence of tetra-n-alkylammonium ions

R. M. Izatt, D. Eatough, J. J. Christensen and C. H. Bartholomew, J. Chem. Soc. A, 1969, 45 DOI: 10.1039/J19690000045

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