Issue 0, 1969
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Crystal structure of dichlorodimethylbis(pyridine N-oxide)tin(IV)

E. A. Blom,   Bruce R. Penfold  and  Ward T. Robinson  

Abstract

X-Ray structure analysis of (Me)2(C5H5NO)2SnCl2 has shown that the compound is a monomeric octahedral trans-complex with a crystallographic centre of symmetry. The crystals are triclinic, space group P[1 with combining macron] with a= 7·25, b= 7·24, c= 8·75 Å, α= 102·6, β= 87·5, γ= 117·2°, and Z= 1. Full-matrix least-squares refinement was carried out to a conventional R of 9·2% for 1007 independent reflexions. Bond lengths are Sn–Cl, 2·58(1); Sn–O, 2·25(2); Sn–CH3, 2·22(2); and N–O, 1·37(2)Å. The angle Sn–O–N is 117(1)° and the dihedral angle between the plane of the pyridine ring and the plane of the atoms Sn–O–N is 83°.

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Article information

DOI
https://doi.org/10.1039/J19690000913
Article type
Paper

J. Chem. Soc. A, 1969, 913-917

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Crystal structure of dichlorodimethylbis(pyridine N-oxide)tin(IV)

E. A. Blom, B. R. Penfold and W. T. Robinson, J. Chem. Soc. A, 1969, 913 DOI: 10.1039/J19690000913

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