Issue 0, 1969
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Crystal and molecular structure of tris[bis(trimethylsilyl)amino]aluminium, Al[N(SiMe3)2]3

G. M. Sheldrick  and  W. S. Sheldrick  

Abstract

The crystal structure of Al[N(SiMe3)2]3 has been determined by single-crystal X-ray diffraction. The crystals are trigonal, space group P[3 with combining macron]1c, with Z= 2 in a unit cell of dimensions a= 15·950 ± 0·009, c= 8·683 ± 0·017 Å. The molecule has D3 symmetry with a dihedral angle of 50° between the AlN3 and AlNSi2 planes. The bond lengths and angles were found to be: Al–N 1·78 ± 0·02, N–Si 1·75 ± 0·01, mean Si–C 1·90 ± 0·02 Å, Al–N–Si 121 ± 1, mean N–Si–C 112 ± 2°.

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Article information

DOI
https://doi.org/10.1039/J19690002279
Article type
Paper

J. Chem. Soc. A, 1969, 2279-2282

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Crystal and molecular structure of tris[bis(trimethylsilyl)amino]aluminium, Al[N(SiMe3)2]3

G. M. Sheldrick and W. S. Sheldrick, J. Chem. Soc. A, 1969, 2279 DOI: 10.1039/J19690002279

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