Issue 0, 1969

Some substitution reactions of amminediethylenetriaminepalladium(II) salts in aqueous solution

Abstract

The rate of aquation and chloride substitution reactions of Pd dien NH32+ have been studied in acid aqueous solution. The replacement of NH3 by Cl follows the expected two-term rate law but is preceded by rapid side reactions involving the opening of one ring of the chelated ligand.

Article information

Article type
Paper

J. Chem. Soc. A, 1969, 2669-2672

Some substitution reactions of amminediethylenetriaminepalladium(II) salts in aqueous solution

J. S. Coe and J. R. Lyons, J. Chem. Soc. A, 1969, 2669 DOI: 10.1039/J19690002669

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