Issue 0, 1970

Complexes of molybdenum(VI) and molybdenum(V) with dithiocarbamate, dithiocarbonate, and phosphorothiolothionate

Abstract

Complexes Mo2O3B4(B = diethyl dithiocarbamate, O-ethyldithiocarbonate, or diethyl or diphenyl-phosphorothiolothionate), MoO2B2, and Mo2O3B2(CH3CO2)2(B = diethyl dithiocarbamate), and MoOB2(C5H5N)(B = ethyldithiocarbonate) have been prepared. Their electronic, i.r., and 1H n.m.r. spectra are reported. For these and other oxomolybdenum(V) complexes a correlation is found between Mo–O stretching frequencies and the frequency of the first dd transition.

Article information

Article type
Paper

J. Chem. Soc. A, 1970, 1702-1708

Complexes of molybdenum(VI) and molybdenum(V) with dithiocarbamate, dithiocarbonate, and phosphorothiolothionate

R. N. Jowitt and P. C. H. Mitchell, J. Chem. Soc. A, 1970, 1702 DOI: 10.1039/J19700001702

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