Issue 0, 1969

Molecular polarisability. The dipole moments and molar Kerr constants of some para-substituted anisoles

Abstract

Dipole moments and molar Kerr constants are reported for the molecules p-XC6H4·OMe (X = H, Me, Cl, Br, l, NO2, or CN) examined as solutes in carbon tetrachloride and benzene. The experimental data are analysed to indicate that (a) the Car–O–C group is virtually coplanar with the aromatic ring if X = NO2 or CN; for X = H, Me, or halogen, the apparent dihedral angle between the planes is ca. 20°(b) stereospecific benzene–solute complex formation occurs in the aromatic solvent.

Article information

Article type
Paper

J. Chem. Soc. B, 1969, 666-669

Molecular polarisability. The dipole moments and molar Kerr constants of some para-substituted anisoles

M. J. Aroney, R. J. W. Le Fèvre, R. K. Pierens and M. G. N. The, J. Chem. Soc. B, 1969, 666 DOI: 10.1039/J29690000666

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements