Issue 0, 1967

Organomercury compounds. Part V. Preparations of pentachlorophenylmercury compounds by decarboxylation reactions

Abstract

Mercuric pentachlorobenzoate and arylmercuric pentachlorobenzoates, RHgOCO·C6Cl5(R = Ph, p-MeC6H4, or p-MeO·C6H4), undergo decarboxylation in boiling pyridine to give bispentachlorophenylmercury and arylpentachlorophenylmercurials, respectively. Reactions of phenylmercuric chloride, p-tolymercuric chloride, and mercuric chloride with thallous pentachlorobenzoate in boiling pyridine yield pentachlorophenylphenylmercury, pentachlorophenyl-p-tolymercury, and pentachlorophenylmercuric chloride, respectively.

Article information

Article type
Paper

J. Chem. Soc. C, 1967, 2313-2314

Organomercury compounds. Part V. Preparations of pentachlorophenylmercury compounds by decarboxylation reactions

G. B. Deacon and P. W. Felder, J. Chem. Soc. C, 1967, 2313 DOI: 10.1039/J39670002313

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