The reaction between 1,4,8,11-tetraazacyclotetradecanecopper(II) perchlorate and sodium sulfide gave a transparent amorphous CuS film supported on a polyethylene substrate. The surface electrical resistivity of the film was ca. 10 k Ω□ at 300 K and showed a metal-like temperature dependence down to 250 K.
M. Inoue, C. Cruz-Vazquez, M. B. Inoue and Q. Fernando, J. Mater. Chem., 1992, 2, 761 DOI: 10.1039/JM9920200761
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