Issue 0, 1973
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Lignans and related phenols. Part XIV. Selective oxidation of aryltetrahydronaphthalenes

David C. Ayres  and  John A. Harris  

Abstract

The selective oxidation of aryltetrahydronaphthalene lignans by periodate and Fremy's salt has been demonstrated. Steric factors were evident in the reactions of the 5,8-quinone (II), which only underwent Thiele acetylation following its isomerisation to the flexible ‘picro’ derivative (III). U.v. irradiation of the quinone afforded a novel synthesis of a wholly aromatic analogue (V). Configurations were assigned on the basis of c.d. measurements.

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Article information

DOI
https://doi.org/10.1039/P19730002059
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1973, 2059-2063

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Lignans and related phenols. Part XIV. Selective oxidation of aryltetrahydronaphthalenes

D. C. Ayres and J. A. Harris, J. Chem. Soc., Perkin Trans. 1, 1973, 2059 DOI: 10.1039/P19730002059

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