Issue 0, 1973
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Pyrroles and related compounds. Part XXIV. Separation and oxidative degradation of chlorophyll derivatives

George W. Kenner,   Stuart W. McCombie  and  Kevin M. Smith  

Abstract

A convenient, large-scale method for separation of the aand b series metal-free chlorophyll derivatives is described, utilising the Girard ‘T’ reagent with subsequent chromatography. Efficient procedures for conversion of phaeophytin-a(3) into rhodoporphyrin-XV dimethyl ester (1) and the corresponding 2-vinyl compound (2), involving the classical oxidation to purpurin derivatives, followed by further degradation, are described: n.m.r. data for several important chlorophyll degradation products are reported. Novel oxidative reactions of the isocyclic ring in methyl mesopyrophaeophorbide-a(19) are also described.

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Article information

DOI
https://doi.org/10.1039/P19730002517
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1973, 2517-2523

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Pyrroles and related compounds. Part XXIV. Separation and oxidative degradation of chlorophyll derivatives

G. W. Kenner, S. W. McCombie and K. M. Smith, J. Chem. Soc., Perkin Trans. 1, 1973, 2517 DOI: 10.1039/P19730002517

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