SCHEDULED MAINTENANCE
The electrochemical oxidation of alkanes in weak acidic solution (CH2Cl2–CF3·CO2H) was investigated. The non-statistical isomer distribution of n-decane oxidation products seems to parallel slight differences in the reactivity of the CH2 groups. A mechanism involving free carbocations is suggested.
H. P. Fritz and T. Würminghausen, J. Chem. Soc., Perkin Trans. 1, 1976, 610 DOI: 10.1039/P19760000610
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