Issue 0, 1980
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Improved methods for conversion of primary amines into bromides

Alan R. Katritzky,   Fatima Al-Omran,   Ranjan C. Patel  and  Sukhpal S. Thind  

Abstract

N-Alkyl- and N-benzyl-4-p-chlorophenyl-2,3,5,6-tetraphenyl-N-alkyl- and N-benzyl-2,3,4,5,6-pentaphenyl-, and N-alkyl- and N-benzyl-2,4,6-triphenyl-pyridinium bromides on pyrolysis at 180–220 °C give the corresponding alley and benzyl bromides in high yield. 1-Benzyl-5,6-dihydro-2,4-diphenylbenzo[h]quinolinium trifluoromethanesulphonate gave benzyl bromide on heating with KBr in dimethylformamide at 100 °C, and n-octyl bromide (80%) was obtained from the corresponding pentacyclic bromide in refluxing acetonitrile.

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Article information

DOI
https://doi.org/10.1039/P19800001890
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1980, 1890-1894

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Improved methods for conversion of primary amines into bromides

A. R. Katritzky, F. Al-Omran, R. C. Patel and S. S. Thind, J. Chem. Soc., Perkin Trans. 1, 1980, 1890 DOI: 10.1039/P19800001890

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