Issue 0, 1986

Reaction of C-(triphenylphosphinimido)hydrazones with isocyanates as a route to 5-arylamino- and 5-alkylamino-1H-1,2,4-triazoles

Abstract

Treatment of C-(triphenylphosphinimido)hydrazone (1) with aryl and alkyl isocyanates results in 5-arylamino- and 5-alkylamino-1H-1,2,4-triazoles (5), often accompanied by a minor quantity of the triazol-5-one (7). The related ortho-acyl-substituted substrates (8) react with phenyl isocyanate to give [1,2,4]triazolo[1,5-a]quinazolines (12) or (13) through the intermediacy of aminotriazoles (11).

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1986, 2177-2179

Reaction of C-(triphenylphosphinimido)hydrazones with isocyanates as a route to 5-arylamino- and 5-alkylamino-1H-1,2,4-triazoles

L. Bruché, L. Garanti and G. Zecchi, J. Chem. Soc., Perkin Trans. 1, 1986, 2177 DOI: 10.1039/P19860002177

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