Issue 0, 1987
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Studies on selected transformations of some fluoromethanephosphonate esters

G. Michael Blackburn,   David Brown,   Stephen J. Martin  and  Martin J. Parratt  

Abstract

The thermal stability of α-fluoromethanephosphonate carbanions decreases in the series CHF > CF2 > CFCl. Acylation products of the difluoromethanephosphonate carbanion show high electrophilic reactivity which results in the immediate formation of secondary products. This behaviour is not observed for the monofluoromethanephosphonate carbanion. Attempts to acylate or phosphorylate the chiorofluoromethanephosphonate carbanion unexpectedly provide esters of fluoromethylenebisphosphonic acid as products. Some physical characteristics of fluoromethanephosphonic acids are described.

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Article information

DOI
https://doi.org/10.1039/P19870000181
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1987, 181-186

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Studies on selected transformations of some fluoromethanephosphonate esters

G. M. Blackburn, D. Brown, S. J. Martin and M. J. Parratt, J. Chem. Soc., Perkin Trans. 1, 1987, 181 DOI: 10.1039/P19870000181

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