Issue 5, 1973
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Iodination and iodo-compounds. Part IV. The effect of substituents and solvent composition on the rate of aromatic iodination by means of the tri-iodine cation

Judah Arotsky,   A. Carl Darby  and  John B. A. Hamilton  

Abstract

The rate and products of the reaction between each of a range of deactivated substituted benzenes and the tri-iodine cation, in sulphuric acid solution, have been investigated. The rate constants may be correlated by the electrophilic substituent constants σ+ giving a value for the reaction constant ρ=–6·4. The kinetic isotope effect for the iodination of benzoic acid was found to be kH/kD= 2. Further details of the solvent effect are reported.

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Article information

DOI
https://doi.org/10.1039/P29730000595
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1973, 595-599

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Iodination and iodo-compounds. Part IV. The effect of substituents and solvent composition on the rate of aromatic iodination by means of the tri-iodine cation

J. Arotsky, A. C. Darby and J. B. A. Hamilton, J. Chem. Soc., Perkin Trans. 2, 1973, 595 DOI: 10.1039/P29730000595

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