Issue 8, 1975
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

The stabilities of Meisenheimer complexes. Part X. Association of 1,1-dimethoxy-complexes with cations

Michael R. Crampton  

Abstract

Equilibrium and kinetic measurements are reported for the formation in methanol of 1,1-dimethoxy-Meisenheimer complexes from activated aromatic anisoles and sodium methoxide in the presence of 18-crown-6-ether. Comparison of the results with those obtained without crown ether leads to the suggestion that sodium ions associate with the Meisenheimer anions through interaction with the oxygen atoms of the methoxy-groups at C(1) and the ortho-substituents.

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Article information

DOI
https://doi.org/10.1039/P29750000825
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1975, 825-826

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The stabilities of Meisenheimer complexes. Part X. Association of 1,1-dimethoxy-complexes with cations

M. R. Crampton, J. Chem. Soc., Perkin Trans. 2, 1975, 825 DOI: 10.1039/P29750000825

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