Issue 2, 1984

Electrophilic ipso-substitutions. Part 3. Reactions of 3-substituted indoles,4-substituted N,N-dimethylanilines, and 1- and 3-substituted indolizines with nitrous acid

Abstract

Reactions of 3-substituted indoles, N,N-dimethylanilines, and 1- and 3-substituted indolizines with nitrous acid yield products of ipso-substitutions, essentially the corresponding nitro-derivatives. An electron transfer process is proposed for the initial step, on the basis of reaction products, e.s.r. evidence, and substrate oxidation potentials.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1984, 165-169

Electrophilic ipso-substitutions. Part 3. Reactions of 3-substituted indoles,4-substituted N,N-dimethylanilines, and 1- and 3-substituted indolizines with nitrous acid

M. Colonna, L. Greci and M. Poloni, J. Chem. Soc., Perkin Trans. 2, 1984, 165 DOI: 10.1039/P29840000165

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