Issue 4, 1986
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Exothermic isomerization of water-soluble quadricyclanes to norbornadienes by soluble and insoluble catalysts

Kazuhiro Maruyama,   Hitoshi Tamiaki  and  Shigeki Kawabata  

Abstract

Water-soluble quadricyclane derivatives (1) were stable in an aqueous sodium carbonate solution, but addition of a catalytic amount of water-soluble cobalt porphyrin complexes (3) induced rapid and quantitative isomerization of (1) to norbornadiene derivatives (2) under release of heat. Insoluble catalysts (4) prepared by adsorption of Co-TPP or Co-Pc on activated carbon were similarly active as the soluble analogues. They were stable enough to keep high activities for recycling use.

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Article information

DOI
https://doi.org/10.1039/P29860000543
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1986, 543-549

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Exothermic isomerization of water-soluble quadricyclanes to norbornadienes by soluble and insoluble catalysts

K. Maruyama, H. Tamiaki and S. Kawabata, J. Chem. Soc., Perkin Trans. 2, 1986, 543 DOI: 10.1039/P29860000543

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