Issue 4, 1989
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Kinetics and mechanism of the reaction between carbon dioxide and amines in aqueous solution

John E. Crooks  and  J. Paul Donnellan  

Abstract

Rate constants, ΔH‡ and ΔS‡ have been measured by the conductimetric stopped-flow technique for the reaction of carbon dioxide in aqueous solution with the primary amines 2-methoxyethylamine, 2-aminoethanol, 3-aminopropan-1-ol, 2-aminopropan-2-ol, DL-aminopropan-2-ol and the secondary amines 1,1′-iminodipropan-2-ol, 2-amino-2-(hydroxymethyl) propane-1,3-diol, 2,2′-iminodiethanol, 2,2,6,6-tetramethylpiperidin-4-ol, and morpholine. The observed first-order rate constants fit the equation kobs=kAM[R2NH]2+kW[R2NH][H2O]. The much-quoted Danckwerts mechanism is shown to be unlikely.

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Article information

DOI
https://doi.org/10.1039/P29890000331
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1989, 331-333

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Kinetics and mechanism of the reaction between carbon dioxide and amines in aqueous solution

J. E. Crooks and J. P. Donnellan, J. Chem. Soc., Perkin Trans. 2, 1989, 331 DOI: 10.1039/P29890000331

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