Volume 62, 1966

Pseudo-potential model for hard sphere mixtures

Abstract

The pseudo pair potential theory of mixtures developed by Salsburg1 has been tested by carrying out Monte Carlo calculations for hard sphere systems of radius ratios 5 : 3 and 3 : 1 at low and moderate densities. Comparison between the results obtained by use of the pseudo-potential model with those obtained earlier by direct Monte Carlo simulation studies2, 3 for such mixtures shows that the model is not a good approximation. An explanation of the observed discrepancies is proposed.

Article information

Article type
Paper

Trans. Faraday Soc., 1966,62, 3039-3043

Pseudo-potential model for hard sphere mixtures

J. A. Barker, M. Rigby and E. B. Smith, Trans. Faraday Soc., 1966, 62, 3039 DOI: 10.1039/TF9666203039

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