Volume 65, 1969
From the journal:

Transactions of the Faraday Society

Molecular structure of S2Cl2

B. Beagley,   G. H. Eckersley,   D. P. Brown  and  MissD. Tomlinson  

Abstract

The molecular structure of S2Cl2 has been determined accurately by electron diffraction. The ClSSCl chain configuration has the dimensions: S—Cl = 2.057 ± 0.002 Å, S—S = 1.931 ± 0.005 Å, SSCl = 108.2 ± 0.3°, ϕ(the dihedral angle between the two SSCl planes)= 84.8 ± 1.3°. The two bond distances occur within a single peak of the radial distribution curve; the resulting correlation problem was solved by carrying out refinements with constrained amplitudes. The study confirms the absence of the pyramidal isomer S = SCl2, but the existence of SClClS cannot be ruled out entirely from the electron diffraction results alone. The structure of S2Cl2 is compared with that of S2F2 where the S = SF2 isomer predominates.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/TF9696502300
Article type
Paper

Trans. Faraday Soc., 1969,65, 2300-2307

Permissions

Request permissions

Molecular structure of S2Cl2

B. Beagley, G. H. Eckersley, D. P. Brown and D. Tomlinson, Trans. Faraday Soc., 1969, 65, 2300 DOI: 10.1039/TF9696502300

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements