Volume 67, 1971

Molecular motion in the glassy state. The effect of temperature and pressure on the dielectric β relaxation of polyvinyl chloride

Abstract

The dielectric β relaxation of polyvinyl chloride has been studied in the ranges of temperature, pressure and frequency, 296 to 353 K, 1 × 105 to 3 × 108 N m–2 and 1 to 105 Hz. Detailed results are discussed in terms of current concepts of the α, β and (αβ) relaxations which occur in amorphous polymers and in small molecule glass forming systems.

Article information

Article type
Paper

Trans. Faraday Soc., 1971,67, 1971-1979

Molecular motion in the glassy state. The effect of temperature and pressure on the dielectric β relaxation of polyvinyl chloride

G. Williams and D. C. Watts, Trans. Faraday Soc., 1971, 67, 1971 DOI: 10.1039/TF9716701971

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