Issue 14, 1997
From the journal:

Chemical Communications

New thermal rearrangements of vinylogous ketoketenes and related intermediates

Gary A. Cartwright,   Robert O. Gould  and  Hamish McNab  

Abstract

2-Oxopyran-5-carbaldehydes (e.g. 3) containing a trapping group in the 5-position rearrange thermally by a sequence involving electrocyclic ring opening, E/Z isomerisation and ring closure; a similar strategy has enabled the first cases of thermal interconversion of pyran-2-ones and 2-pyridones, and of automerisation of 2-pyridones to be identified.

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Article information

DOI
https://doi.org/10.1039/A702395B
Article type
Paper

Chem. Commun., 1997, 1293-1294

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New thermal rearrangements of vinylogous ketoketenes and related intermediates

G. A. Cartwright, R. O. Gould and H. McNab, Chem. Commun., 1997, 1293 DOI: 10.1039/A702395B

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