Issue 5, 1998
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Kinetics and mechanism of the formation of mono- and di-phthalate esters catalysed by titanium and tin alkoxides

Nicholas J. Hinde  and  C. Dennis Hall  

Abstract

The kinetics and mechanism of the formation of phthalate mono-esters and phthalate di-esters from phthalic anhydride and a variety of mono- and di-hydric alcohols are reported and discussed. The kinetic work is extended to a mechanistic study of the same reactions using titanium tetra-n-butoxide and tri-n-butyltin ethoxide as catalysts. The results support a mechanism involving alkoxy ligand exchange at the metal as a crucial step in the catalysis.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/A708468D
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1998, 1249-1256

Permissions

Request permissions

Kinetics and mechanism of the formation of mono- and di-phthalate esters catalysed by titanium and tin alkoxides

N. J. Hinde and C. Dennis Hall, J. Chem. Soc., Perkin Trans. 2, 1998, 1249 DOI: 10.1039/A708468D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements