Cerium(IV) oxidative dimerisations of 4,4′-bis(trimethylsilyl)-2,2′:5′,2′′-terthiophene and the quaterthienyl analogue 1c gave the corresponding sexi- and octi-thiophenes; the latter have been used to prepare α-linked hexadecithiophene and tetracosithiophene derivatives.
A. H. Mustafa and M. K. Shepherd, Chem. Commun., 1998, 2743 DOI: 10.1039/A806600K
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