The well known methyltrioxorhenium-catalysed epoxidation of alkenes with aqueous H2O2 is significantly improved by conducting the epoxidation in trifluoroethanol; excellent reaction rates and yields can be obtained for a variety of (terminal) alkenes with only 0.1 mol% of catalyst.
M. C. A. van Vliet, I. W. C. E. Arends and R. A. Sheldon, Chem. Commun., 1999, 821 DOI: 10.1039/A902133G
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