Issue 5, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

A facile preparation of indium enolates and their Reformatsky- and Darzens-type reactions

Tsunehisa Hirashita,a   Kenji Kinoshita,a   Hatsuo Yamamura,a   Masao Kawaia  and  Shuki Araki*a  

* Corresponding authors

a Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, Japan

Abstract

Indium enolates were readily prepared by transmetalation of lithium enolates with indium trichloride, and were subsequently reacted with aldehydes to give β-hydroxy esters in high yields. Indium α-bromo enolates were also prepared and reacted with carbonyl compounds to give Darzens-type α,β-epoxy carbonyl products.

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Article information

DOI
https://doi.org/10.1039/A907334E
Article type
Paper
Submitted
10 Sep 1999
Accepted
04 Jan 2000
First published
07 Feb 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 825-828

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A facile preparation of indium enolates and their Reformatsky- and Darzens-type reactions

T. Hirashita, K. Kinoshita, H. Yamamura, M. Kawai and S. Araki, J. Chem. Soc., Perkin Trans. 1, 2000, 825 DOI: 10.1039/A907334E

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