Issue 18, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Strategies for protodesilylation of C-2 trialkylsilyl terminal alkenes

James C. Anderson*a  and  Alice Flahertya  

* Corresponding authors

a School of Chemistry, University of Nottingham, Nottingham, UK
E-mail: j.anderson@nottingham.ac.uk

Abstract

The mild and high yielding protodesilylation of C-2 trialkylsilyl terminal alkenes can be effected via a hydroboration–Peterson elimination protocol or, in the case of the phenyldimethylsilyl analogues, a one pot procedure using t-BuOK–18-C-6–TBAF can be used.

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Article information

DOI
https://doi.org/10.1039/B006049F
Article type
Communication
Submitted
26 Jul 2000
Accepted
17 Aug 2000
First published
24 Aug 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 3025-3027

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Strategies for protodesilylation of C-2 trialkylsilyl terminal alkenes

J. C. Anderson and A. Flaherty, J. Chem. Soc., Perkin Trans. 1, 2000, 3025 DOI: 10.1039/B006049F

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