Issue 79, 2002
From the journal:

CrystEngComm

α-Polonium coordination networks constructed from bis(imidazole) ligands

Brendan F. Abrahams,a   Bernard F. Hoskins,a   Richard Robson*a  and  Damian A. Slizysa  

* Corresponding authors

a School of Chemistry, University of Melbourne, Victoria 3010, Australia
E-mail: R.Robson@unimelb.edu.au

Abstract

Two types of bis(imidazole) ligands – 1,4-bis(imidazol-1-ylmethyl)benzene (bix) and 1,4-bis(imidazolyl)-2-butyne (bib) – have been used to bridge octahedral metal centres and form simple cubic networks. Crystal structures of Cd(bix)3(ClO4)2, Cd(bix)3(NO3)2, Zn(bib)3(BF4)2 and Co(bib)3(NO3)2 reveal that all possess the α-polonium topology and are triply interpenetrating.

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Article information

DOI
https://doi.org/10.1039/B204849C
Article type
Paper
Submitted
21 May 2002
Accepted
23 Jul 2002
First published
31 Jul 2002

CrystEngComm, 2002,4, 478-482

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α-Polonium coordination networks constructed from bis(imidazole) ligands

B. F. Abrahams, B. F. Hoskins, R. Robson and D. A. Slizys, CrystEngComm, 2002, 4, 478 DOI: 10.1039/B204849C

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