Issue 5, 2003
From the journal:

Chemical Communications

Thermostable sulfated 2–4 nm tetragonal ZrO2 with high loading in nanotubes of SBA-15: a superior acidic catalytic material

M. V. Landau,*a   L. Titelman,a   L. Vradmanb  and  P. Wilsona  

* Corresponding authors

a Blechner Center for Industrial Catalysis and Process Development, Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva-84105, Israel
E-mail: mlandau@bgumail.bgu.ac.il

b Department of Chemical Engineering, Negev Academic College of Engineering, Beer-Sheva 84100, Israel

Abstract

The high-loaded (48–60 wt.%) 2–4 nm tetragonal ZrO2 phase inserted in mesostructured silica SBA-15 by chemical solution decomposition (CSD) of Zr(n-PrO)4 and activated at 873 K displayed ∼3 times higher capacity for surface sulfate ions and, respectively, 1.5–2.2 times higher catalytic activity per gram of SO4-ZrO2/SBA-15 composite in condensation of MeOH with t-BuOH and dehydration of isopropanol compared with the regular bulk sulfated zirconia material.

Graphical abstract: Thermostable sulfated 2–4 nm tetragonal ZrO2 with high loading in nanotubes of SBA-15: a superior acidic catalytic material

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B211585A
Article type
Communication
Submitted
26 Nov 2002
Accepted
09 Jan 2003
First published
03 Feb 2003

Chem. Commun., 2003, 594-595

Permissions

Request permissions

Thermostable sulfated 2–4 nm tetragonal ZrO2 with high loading in nanotubes of SBA-15: a superior acidic catalytic material

M. V. Landau, L. Titelman, L. Vradman and P. Wilson, Chem. Commun., 2003, 594 DOI: 10.1039/B211585A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements