Issue 18, 2003
From the journal:

Chemical Communications

2 ∶ 1 Ba/Ti(iv) Heterobimetallic complex based on two calix[6]arenes

Antonella J. Petrella,a   Nicholas K. Roberts,a   Donald C. Craig,a   Colin L. Rastonb  and  Robert N. Lamba  

a School of Chemical Sciences, University of New South Wales, Sydney, Australia
E-mail: r.lamb@unsw.edu.au

b School of Biomedical and Chemical Sciences, University of Western Australia, Crawley, Perth Australia
E-mail: clraston@chem.uwa.edu.au

Abstract

Reaction of p-But-calix[6]arene with barium metal in methanol then [Ti(OPri)4] affords a heterobimetallic complex with a central Ti(IV) attached to two calix[6]arenes in the 1,3-alternate conformation, each with an endo-barium sharing common phenolate groups with the titanium centre.

Graphical abstract: 2 ∶ 1 Ba/Ti(iv) Heterobimetallic complex based on two calix[6]arenes

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Article information

DOI
https://doi.org/10.1039/B302346J
Article type
Communication
Submitted
27 Feb 2003
Accepted
28 Jul 2003
First published
12 Aug 2003

Chem. Commun., 2003, 2288-2289

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2 ∶ 1 Ba/Ti(IV) Heterobimetallic complex based on two calix[6]arenes

A. J. Petrella, N. K. Roberts, D. C. Craig, C. L. Raston and R. N. Lamb, Chem. Commun., 2003, 2288 DOI: 10.1039/B302346J

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