Issue 71, 2003

Structural relationship of two coordination polymers of Cu(i) with the ligand ethanediyl bis(isonicotinate)

Abstract

The flexible ligand ethanediyl bis(isonicotinate), L, is used as linking unit for Cu(I) ions in a coordination polymer. Two different structures of one-dimensional chains can be obtained, mainly depending on the co-crystallising solvent. Weak interactions such as hydrogen bonding and pi–stacking, and the exclusion of solvent molecules are responsible for the slow transformation of one compound into the other in the mother liquor.

Graphical abstract: Structural relationship of two coordination polymers of Cu(i) with the ligand ethanediyl bis(isonicotinate)

Supplementary files

Article information

Article type
Paper
Submitted
06 Aug 2003
Accepted
16 Oct 2003
First published
29 Oct 2003

CrystEngComm, 2003,5, 405-410

Structural relationship of two coordination polymers of Cu(I) with the ligand ethanediyl bis(isonicotinate)

A. Y. Robin, K. M. Fromm, H. Goesmann and G. Bernardinelli, CrystEngComm, 2003, 5, 405 DOI: 10.1039/B309410C

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