Issue 6, 2005

Structural manifestations of the cheletropic reaction

Abstract

Examination of selected cyclopentenone derivatives which are fixed into the boat conformation reveals structural deviations from ‘normal’ C–C(O) and C[double bond, length as m-dash]O bond distances consistent with the early stages of the cheletropic extrusion of carbon monoxide.

Graphical abstract: Structural manifestations of the cheletropic reaction

Supplementary files

Article information

Article type
Communication
Submitted
22 Nov 2004
Accepted
31 Jan 2005
First published
14 Feb 2005

Org. Biomol. Chem., 2005,3, 972-974

Structural manifestations of the cheletropic reaction

G. Y. Wooi and J. M. White, Org. Biomol. Chem., 2005, 3, 972 DOI: 10.1039/B417538G

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