Issue 39, 2006
From the journal:

Dalton Transactions

Pyridinyloxazolidines: versatile scaffolds for chiral catalyst construction†

Steven A. Cardile,a   Michael C. Jenningsab  and  Nathan D. Jones*a  

* Corresponding authors

a Department of Chemistry, The University of Western Ontario, London, Ontario, Canada
E-mail: njones26@uwo.ca
Fax: 1 519 661 3022
Tel: 1 519 661 2111 ext. 84456

b X-Ray Crystallographic Laboratory, The University of Western Ontario, London, Ontario, Canada
E-mail: mjenning@uwo.ca
Fax: 1 519 661 3022
Tel: 1 519 661 2111 ext. 82167

Abstract

Pyridinyloxazolidines are structurally versatile chiral ligand frameworks that are easily made and coordinated to Pd(II); the resulting complexes, which show significant steric and electronic differences from their oxazoline counterparts, as well as intermolecular H-bonding in the solid state, can be isolated in diastereomerically pure form and are remarkably resistant to hydrolysis.

Graphical abstract: Pyridinyloxazolidines: versatile scaffolds for chiral catalyst construction

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Article information

DOI
https://doi.org/10.1039/B610079A
Article type
Paper
Submitted
14 Jul 2006
Accepted
21 Jul 2006
First published
08 Aug 2006

Dalton Trans., 2006, 4672-4678

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Pyridinyloxazolidines: versatile scaffolds for chiral catalyst construction

S. A. Cardile, M. C. Jennings and N. D. Jones, Dalton Trans., 2006, 4672 DOI: 10.1039/B610079A

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